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Polymers
Volume 16
Issue 11
10.3390/polym16111539
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Open AccessArticle
by Zhipeng Li SciProfilesScilitPreprints.orgGoogle Scholar Luxia Zhang SciProfilesScilitPreprints.orgGoogle Scholar Xiangyu Han SciProfilesScilitPreprints.orgGoogle Scholar Qinchen An SciProfilesScilitPreprints.orgGoogle Scholar Mengying Chen SciProfilesScilitPreprints.orgGoogle Scholar Zichang Song SciProfilesScilitPreprints.orgGoogle Scholar Linyi Dong SciProfilesScilitPreprints.orgGoogle Scholar Xianhua Wang SciProfilesScilitPreprints.orgGoogle Scholar Yang Yu SciProfilesScilitPreprints.orgGoogle Scholar
Zhipeng LiLuxia ZhangXiangyu HanQinchen AnMengying ChenZichang SongLinyi DongXianhua Wang
and Yang Yu
Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics, School of Pharmacy, Tianjin Medical University, Tianjin 300070, China
*
Authors to whom correspondence should be addressed.
†
These authors contributed equally to this work.
Polymers 2024, 16(11), 1539; https://doi.org/10.3390/polym16111539 (registeringDOI)
Submission received: 31 March 2024/Revised: 20 May 2024/Accepted: 25 May 2024/Published: 29 May 2024
(This article belongs to the Section Polymer Chemistry)
Abstract
Sample pretreatment is a key step for qualitative and quantitative analysis of trace substances in complex samples. Cis-dihydroxyl (cis-diol) group-containing substances exist widely in biological samples and can be selectively bound by boronate affinity adsorbents. Based on this, in this article, we proposed a simple method for the preparation of novel spherical three-dimensionally ordered macropore (3DOM) materials based on a combination of the boronate affinity technique and colloidal crystal template method. The prepared 3DOM materials were characterized using Fourier transform–infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, and thermo-gravimetric analysis, and results showed that they possessed the characteristics of a high specific surface area, high porosity, and more boronic acid recognition sites. The adsorption performance evaluation results showed that the maximum adsorption capacity of the boron affinity 3DOMs on ovalbumin (OVA) could reach to 438.79 mg/g. Kinetic and isothermal adsorption experiments indicated that the boronate affinity 3DOM material exhibited a high affinity and selectivity towards OVA and adenosine. Sodium dodecyl sulfate–polyacrylamide gel electrophoresis analysis of the proteins in egg whites was conducted and proved that the glycoprotein in the egg whites could be separated and enriched with a good performance. Therefore, a novel boronate affinity 3DOM material a with highly ordered and interconnected pore structure was prepared and could be applied in the separation and enrichment of molecules with cis-diol groups from complex samples with a good selectivity, efficiency, and high throughput.
Keywords: cis-dihydroxyl; boronbate affinity; 3DOM; colloidal templating method; microspheres
Share and Cite
MDPI and ACS Style
Li, Z.; Zhang, L.; Han, X.; An, Q.; Chen, M.; Song, Z.; Dong, L.; Wang, X.; Yu, Y.Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials. Polymers 2024, 16, 1539.https://doi.org/10.3390/polym16111539
AMA Style
Li Z, Zhang L, Han X, An Q, Chen M, Song Z, Dong L, Wang X, Yu Y.Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials. Polymers. 2024; 16(11):1539.https://doi.org/10.3390/polym16111539
Chicago/Turabian Style
Li, Zhipeng, Luxia Zhang, Xiangyu Han, Qinchen An, Mengying Chen, Zichang Song, Linyi Dong, Xianhua Wang, and Yang Yu.2024. "Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials" Polymers 16, no. 11: 1539.https://doi.org/10.3390/polym16111539
Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.
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MDPI and ACS Style
Li, Z.; Zhang, L.; Han, X.; An, Q.; Chen, M.; Song, Z.; Dong, L.; Wang, X.; Yu, Y.Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials. Polymers 2024, 16, 1539.https://doi.org/10.3390/polym16111539
AMA Style
Li Z, Zhang L, Han X, An Q, Chen M, Song Z, Dong L, Wang X, Yu Y.Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials. Polymers. 2024; 16(11):1539.https://doi.org/10.3390/polym16111539
Chicago/Turabian Style
Li, Zhipeng, Luxia Zhang, Xiangyu Han, Qinchen An, Mengying Chen, Zichang Song, Linyi Dong, Xianhua Wang, and Yang Yu.2024. "Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials" Polymers 16, no. 11: 1539.https://doi.org/10.3390/polym16111539
Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.
Polymers,EISSN 2073-4360,Published by MDPI
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